Process Modeling and Simulation of Ammonia Production from Natural Gas: Control and Response Analysis

Abstract

Optimal production of ammonia (NH₃) using natural gas is necessary in order to make it available for wide range of applications including the manufacture of fertilizers, fuel for transportation and during synthesis of some chemicals. Achieving this would require strategic implementation of a control scheme to simulated ammonia production, capable of ensuring adequate realization of production targets. The work involves ASPEN Plus modeling, simulation, sensitivity analysis and control of NH₃ production process. Steam/carbon ratio, conversion of CH₄, removal of carbon dioxide (CO₂) and carbon monoxide (CO), hydrogen/nitrogen ratio and heat exchanger and separator temperatures were identified as requiring control in units any of these specifically impacts. As a result, approximately 176 tons of NH₃ was realized daily based on the simulation results and can be scaled-up using a calculated factor equivalent to 1.1375 to 200 tons/day capacity, in this design. Sensitivity analysis resulting in control of certain unit parameters is effective in ensuring process safety, maximum yield of important end-products and reduction in the cost of operation